The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Sulfur compounds / Inorganic S-compounds / FSO3 / CobosCroce(2007)_403K_260-275nm(II)

DATAFILE: FSO3_CobosCroce(2007)_403K_260-275nm(II).txt
NAME: fluorosulfate radical
FORMULA: FSO3
AUTHOR(YEAR): CobosCroce(2007)
T: 403K
λ: 260-275nm(II)
BIBLIOGRAPHY: C.J. Cobos and A.E. Croce, "Evidences for a new ultraviolet absorption band of the FSO3 radical", Z. Physik. Chem. 221, 897-909 (2007); DOI: 10.1524/zpch.2007.221.7.897
COMMENTS: The absorption spectrum of (FSO3)2 was measured at 295 K and 240-340 nm

Absorbance data of

E. Castellano, R. Gatti, J.E. Sicre, and H.J. Schumacher, Z. Physik. Chem. (NF) 42, 174-186 (1964),

for equilibrated mixtures of FSO3 and (FSO3)2 at 403 K were employed to derive the molar extinction coefficients of FSO3

The equilibrium concentrations of FSO3 and (FSO3)2 at 403 K were obtained from the equilibrium constant of

C.J. Cobos, A.E. Croce de Cobos, H. Hippler, and E. Castellano, J. Phys. Chem. 93, 3089-3094 (1989)

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